Biodiesel characterization characterization of fame in biodiesel. Hence, there is need for optimal, efficient and safe production of. Transesterification is a principal chemical reaction that occurs in biodiesel production. Algal companies specialized in biodiesel production the following is a list of companies developing processes for the production of biodiesel from algae oil. Kohcatalyzed synthesis of biodiesel was carried out in capillary microreactors with inner diameters of 0. Jul 18, 2016 development of a millimetrically scaled biodiesel transesterification device that relies on dropletbased coaxial fluidics. The monthly biodiesel production report provides data on operations of the u. Economic wise, regional production of microalgae and processing into biofuels will provide great benefits to rural communities. Constant attempts are being made to develop new technology that increases the efficiency and yield of biodiesel production units. Membrane microreactor in biocatalytic transesterification of.
Microreactor technology, however, has proved to be a benchmark to serve this purpose. Micromachines free fulltext kinetic parameter estimation. Mar 23, 2015 biodiesel production produced by transesteri. Proceedings of the asme 2011 international design engineering technical conferences and computers and information in engineering conference.
Continuous biodiesel production with biodiesel was able to. The production of biodiesel from waste vegetable oils through its pretreatment followed by transesterification process in presence of methanol was investigated using a km micromixer. Investigation of factors affect biodiesel production in. Design optimization of a microreactor for the production of biodiesel. Development of a millimetrically scaled biodiesel transesterification device that relies on dropletbased coaxial fluidics. Fourth, smallscale biodiesel production does not take more energy to create than it gives back. The production of biodiesel from waste vegetable oils through its pretreatment followed by transesterification process in presence of methanol was investigated using a km micromixer reactor. Optimization of biodiesel production by various plant. Ultrasoundassisted biodiesel production in microreactors 26 iranian journal of chemical engineering, vol.
Pdf due to a rise in global demand for energy and an increase in greenhouse gases, biodiesel has been accepted as an alternative fuel. Numerical investigation of biodiesel production in. Numerical investigation of biodiesel production in capillary microreactor. Microreactor mr technology in biodiesel production provides production betw een 10 and 100 times faster tha n traditional methods. Cad model of the microreactor rial to build up, which can clog the duct. Although biodiesel production has been commercialized in several countries, it still requires a clean, effective, and environmentfriendly technology to make it costeffective and increase its competency against conventional fossil fuels.
In order to further improve biodiesel yield, an experimental design was employed using the boxbehnken method and analysis of variance. We developed a novel biocatalytic membrane microreactor bmm for continuous transesterification by utilizing an asymmetric membrane as an enzymecarrier for. Biodiesel is a form of diesel fuel derived from plants or animals and consisting of longchain fatty acid esters. Hence, there is need for optimal, efficient and safe production of biodiesel from microalgae. Numerical investigation of biodiesel production in capillary.
A flowthrough enzymatic microreactor for the rapid conversion of triacylglycerols into fatty acid. Design of a microreactor for biodiesel production from algae. Microreactor was utilized to overcome numerous issues of the traditional methods for biodiesel production. Finally, continuous biodiesel production was studied in the microreactors in order. Org, a leading organization in biodiesel research and marketing. Enzymatic approach to biodiesel production journal of.
The maximum conversion obtained was 98%, with residence time of 180 s, at 60 c, 1% wt catalyst concentration. The proposed mathematical model predicted the trend of enzyme catalysed transesterification in a microreactor very well and it was used for further process optimisation. Conclusion this proof of principle experiment demonstrates the utility of microfluidics in the production of biodiesel. Biodiesel production from soybean oil using ionic liquid as a catalyst in a microreactor 106 iranian journal of chemical engineering, vol. Therefore, refined palm oil and ethyl acetate were used as an oil feedstock and reactant in the present study.
Production of microreactor systems by additive manufacturing technology 1university of zagreb, faculty of chemical engineering and technology, zagreb, croatia abstract microreactor. New heterogeneous process for continuous biodiesel. The parameters affecting biodiesel production process such as alcohol to oil molar ratio, catalyst concentration, the presence of tetrahydrofuran thf as a cosolvent, and the volumetric flow rates of. A cellular manufacturing process for a fullscale biodiesel microreactor. Pdf there is a growing interest in the production of biofuels mainly because of environmental protection and energy supply reasons. One such energy source is referred to as biodiesel. Biodiesel production from soybean oil using ionic liquid as a. In the present study, experimental work on continuous biodiesel production using a tshaped microreactor was carried out. The components that support combustion in the oil are the basis for biodiesel. Unlike companies which manufacture biodiesel production equipment biodiesel processor based on outdated, tank technologies, which have been used for over a century, our. Kinetic parameter estimation and mathematical modelling of. Biodiesel has become an increasingly popular fossil fuel substitute in recent years. New heterogeneous process for continuous biodiesel production in.
Usually a catalyst is used to mediate the reaction and bring out quicker reaction rate 1. Biodiesel production from the midwest region petroleum administration for defense district 2 accounted for 75 percent of the united states total. This study focuses on maximizing the yield of microfluidic biodiesel production through the use of microreactors. Basics of biodiesel production biodiesel is an alternative fuel for diesel engines that is gaining attention in the united states after reaching a considerable level of success in europe. In this work, we propose a project for the design and construction of a biodiesel microreactor. Us20090165366a1 microreactor process for making biodiesel. Continuous biodiesel production with biodiesel was.
Introduction biodiesel referees to a dieselequivalent, processed fuel derived from biological. Biodiesel has one of the highest energy balance of any liquid fuel. D deng, s optimization of biodiesel production from edible and nonedible vegetable oils. Catalysts can be used to facilitate biodiesel production, such as metal oxides, metal hydroxides, metal carbonates, alcoholic metal carbonates, alkoxides, mineral acids and enzymes. In the present work, choline hydroxide as a basic ionic liquid catalyst was selected for biodiesel production in micro scale reactor.
Researchers believe that implementation of this technology into biodiesel production could be a next big breakthrough not only in process intensification but also in process economics. It is typically made by chemically reacting lipids such as animal fat, soybean oil. Microreactor manufactured on zortrax m200 printer, visible penetration of blue colored fluid into microreactor mass between the layers engeneering power dd 29 19. Production of microreactor systems by additive manufacturing. In this paper, application and possibilities of microreactor technology in biodiesel production have been discussed. Design optimization of a microreactor for the production of. Oil conversion to biodiesel typically increases with increasing mean microreactor residence time. Thermal and fluid dynamic analysis within a batch microreactor.
Pdf design of a microreactor for biodiesel production from algae. Biodiesel characterization characterization of fame in biodiesel samples was determined by a hp 6890 gas chromatograph with a flame ionization detector fid. Design of a microreactor for biodiesel production from. Numerical simulation of biodiesel synthesis in a continuous. The main issue in this study is to find the effects of methanoloil. Therefore, refined palm oil and ethyl acetate were used as an oil feedstock and. Second, microreactor is proposed as an alternative to conventional, batch reactor in producing. Due to small holdup of hazardous chemicals, mr provides safety. Constant attempts are being made to develop new technology that increases the efficiency and yield of. This can be produced from vegetable oils, animal fats, microalgal oils, waste products of vegetable oil refinery or animal rendering, and used. Purchase advances in biodiesel production 1st edition. Pdf design of a microreactor for biodiesel production from.
We developed a novel biocatalytic membrane microreactor bmm for continuous. Combined production of biodiesel and nontoxic cottonseed meal using twostep twophase solvent extraction. Its primary advantages are that it is one of the most renewable fuels currently available and it is also nontoxic and biodegradable. Microtechnology new paradigm for process industries. The canadian journal of chemical engineering, published by wiley on behalf of the canadian society for chemical engineering, is the forum for publication of high quality original research. The %fame was calculated by gas chromatography using methyl arachidate as an internal standard. This paper discusses the alternative ways to optimize biodiesel production. New heterogeneous process for continuous biodiesel production. Microreactors for production of veins and arteries. Biodiesel from algae oil food and agriculture organization. Biodiesel production, properties, and feedstocks bryan r. This report is an overview of the biodiesel production process on a smallscale basis. Triolein with a 3 molar equivalents of methanol, 100 % conversion triolein to methyl oleate.
The transesterification of sunflower oil using sodium hydroxide, as a catalyst, in a microreactor as a continuous reactor was investigated. The application of microreactors on biodiesel production, may provide a solution for this purpose, for short residence times, high production efficiency and low operating cost and energy consumption in biodiesel production via transesterification. Optimization of biodiesel production from soybean oil in a. The application of microreactors on biodiesel production, may provide a solution for this purpose, for short residence times, high production efficiency and low operating cost. Pdf design of a microreactor for biodiesel production.
Jun 12, 2012 han, wei, charoenwat, rachaneewan, and dennis, brian h. The objective of this study was to investigate the biodiesel production process from refined palm oil. Biodiesel production from soybean oil using ionic liquid. Third, biodiesel is a renewable and clean burning energy source. First, different oils from different plant sources were compared to see the degree of conversion in transesterification reaction and the purity of biodiesel produced. Design optimization of a microreactor for the production. Using a wire coil insert for biodiesel production enhancement in a microreactor. Fourier transform infrared spectroscopy was used to investigate the functional groups present in biodiesel. Algal companies specialized in biodiesel production the following is a list of companies developing processes.
Process intensification of biodiesel production using a tubular. Small scale biodiesel production feasibility report. Han, wei, charoenwat, rachaneewan, and dennis, brian h. Sep 29, 2007 the need for alternative energy sources that combine environmental friendliness with biodegradability, low toxicity, renewability, and less dependence on petroleum products has never been greater. Majid mohadesi, babak aghel, mahmoud maleki and ahmadreza ansari, production of biodiesel from waste cooking oil using a homogeneous catalyst. On the other hand, this microreactor type was discarded due to clogging and a ptfe tubular microreactor was proposed as a better solution for biodiesel production. Maurizio carlini id, sonia castellucci id and andrea mennuni id. Biodiesel production was carried out 15 times faster in a tubular microreactor tmr than a wellmixed batch reactor.
Production of biodiesel from waste vegetable oil via km. Pdf microreactor technology for biodiesel production. Optimization of biodiesel production by various plant sources. Development and assessment of microreactors applied to biodiesel. Biodiesel is a promising alternative fuel due to the shortness of fossil fuels. The main issue in this study is to find the effects of methanoloil molar ratio, catalyst concentration, reaction time and reaction temperature on the percentage of methyl esters conversion fame %. Biodiesel production during february 2020 was 2 million gallons lower than production in january 2020. Astm international originally known as the american society for testing and.
259 801 577 285 834 1367 701 1084 1126 174 488 1044 1202 1274 437 553 1135 1346 1213 1479 39 1181 1139 931 382 737 652 17 416 667 1186 356 269 678 676 1144 744 577